The invention relates to a method for controlling energy storage converters in a large-scale off-grid micro-grid. The method includes the steps of firstly, setting up the large-scale off-grid micro-grid; secondly, conducting primary frequency modulation on the off-grid micro-grid by means of an energy storage power station through a Droop work mode; thirdly, conducting secondary frequency modulation on the off-grid micro-grid; fourthly, conducting thrice frequency modulation on the off-grid micro-grid through a micro-grid energy management module; fifthly, conducting master and slave control on the multiple energy storage converters in the energy storage power station. According to the method, by means of flexible control over the energy storage converters, the problem of reliable power supply for independent power supply systems in remote electricity-free areas or island grids or other areas can be effectively solved, and the power supply systems can independently run in a safe, stable and economical mode. The method is applied to the multi-energy complementation alternating current bus shared type off-grid micro-grid, the multi-machine parallel operation of the energy storage power station is achieved through high-speed master and slave communication in the energy storage power station, and safe, stable and economical running of the micro-grid is achieved through interstation peer-to-peer control of the energy storage power station.