
基本信息:
- 专利标题: 一种降低乙酸酯酸度的方法
- 专利标题(英):Method for reducing acidity of acetate
- 申请号:CN201310124544.4 申请日:2013-06-09
- 公开(公告)号:CN103467285A 公开(公告)日:2013-12-25
- 发明人: 郑铁江 , 李勋波 , 薛建军 , 孙百亚 , 汤洪良 , 陆乐
- 申请人: 百川化工(如皋)有限公司 , 无锡百川化工股份有限公司
- 申请人地址: 江苏省南通市如皋市长江镇(如皋港区)香江路6号
- 专利权人: 百川化工(如皋)有限公司,无锡百川化工股份有限公司
- 当前专利权人: 南通百川新材料有限公司,江苏百川高科新材料股份有限公司
- 当前专利权人地址: 江苏省南通市如皋市长江镇(如皋港区)香江路6号
- 代理机构: 北京一格知识产权代理事务所
- 代理人: 滑春生
- 主分类号: C07C69/14
- IPC分类号: C07C69/14 ; C07C67/08 ; C07C67/48
The invention relates to a method for reducing the acidity of acetate. The method comprises the following steps: carrying out an esterification reaction of raw materials comprising acetic acid and lower fatty alcohol in a loop composed of an esterification kettle and a reboiler by treating concentrated sulfuric acid as a catalyst; allowing a gas phase material steamed after the esterification reaction to go through an acid trap having a polytetrafluoroethylene inner liner, carrying out mass transfer exchange of the obtained gas phase material and a tower bottom liquid from the bottom of an esterification tower in a ceramic filler layer for washing off most acetic acid and most sulfuric acid entrained by a gas phase material flow; connecting different gas phase material flows discharged from the upper portion of the acid trap to feeding ports at different positions of the esterification tower through the valve combination, and carrying out separation and subsequent refining in the esterification tower to reduce the acidity of the acetate. The acetate obtained through adopting the method accords with product acidity requirements of corresponding product standards.
公开/授权文献:
- CN103467285B 一种降低乙酸酯酸度的方法 公开/授权日:2015-03-25
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07C | 无环或碳环化合物 |
------C07C69/00 | 羧酸酯;碳酸酯或卤甲酸酯 |
--------C07C69/02 | .无环饱和一元羧酯,其含有羧基连接非环碳原子或氢 |
----------C07C69/04 | ..甲酸酯 |
------------C07C69/14 | ...一元羟基化合物的 |