
基本信息:
- 专利标题: 重油高效转化催化裂化催化剂及其制备方法
- 申请号:CN201210179961.4 申请日:2012-06-01
- 公开(公告)号:CN103447063B 公开(公告)日:2016-02-10
- 发明人: 高雄厚 , 张海涛 , 李荻 , 谭争国 , 段宏昌 , 李雪礼 , 刘超伟 , 郑云锋 , 黄校亮 , 蔡进军 , 潘志爽 , 孙雪芹
- 申请人: 中国石油天然气股份有限公司
- 申请人地址: 北京市东城区东直门北大街9号中国石油大厦
- 专利权人: 中国石油天然气股份有限公司
- 当前专利权人: 中国石油天然气股份有限公司
- 当前专利权人地址: 北京市东城区东直门北大街9号中国石油大厦
- 代理机构: 北京三友知识产权代理有限公司
- 代理人: 姚亮
- 主分类号: B01J29/00
- IPC分类号: B01J29/00 ; C10G11/05
The present invention provides a catalytic cracking catalyst for heavy oil and preparation methods thereof. The catalyst comprises 2 to 50% by weight of a phosphorus-containing ultrastable rare earth Y-type molecular sieve, 0.5 to 30% by weight of one or more other molecular sieves, 0.5 to 70% by weight of clay, 1.0 to 65% by weight of high-temperature-resistant inorganic oxides, and 0.01 to 12.5% by weight of a rare earth oxide. The phosphorus-containing ultra-stable rare earth Y-type molecular sieve uses a NaY molecular sieve as a raw material. The raw material is subjected to a rare-earth exchange and a dispersing pre-exchange; the molecular sieve slurry is then filtered, washed with water and subjected to a first calcination to obtain a rare earth sodium Y molecular sieve which has been subjected to such "first-exchange first-calcination", wherein the steps of rare earth exchange and dispersing pre-exchange are not restricted in sequence; and then the rare earth sodium Y molecular sieve which has been subjected to "one-exchange one-calcination" is subjected to "second exchange and second calcination" including ammonium exchange and a phosphorus modification, wherein the steps of the ammonium exchange and the phosphorus modification are not restricted in sequence. The steps of the ammonium exchange and the phosphorus modification can be conducted continuously or non-continuously, the second calcination is conducted after the ammonium exchange for reducing sodium, the phosphorus modification can be conducted before or after the second calcination. The catalyst provided by the invention has the characteristics of high heavy oil conversion capacity, high total liquid yield, and high yield of light oil.
公开/授权文献:
- CN103447063A 重油高效转化催化裂化催化剂及其制备方法 公开/授权日:2013-12-18
IPC结构图谱:
B | 作业;运输 |
--B01 | 一般的物理或化学的方法或装置 |
----B01J | 化学或物理方法,例如,催化作用、胶体化学;其有关设备 |
------B01J29/00 | 包含分子筛的催化剂 |