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基本信息:
- 专利标题: 一种二硝基苯连续加氢及其反应热回收利用方法
- 专利标题(英):Method for continuous hydrogenation of dinitrobenzene and recycling of reaction heat thereof
- 申请号:CN201210099312.3 申请日:2012-04-06
- 公开(公告)号:CN103360265A 公开(公告)日:2013-10-23
- 发明人: 何旭斌 , 陶建国 , 朱敬鑫 , 孟明 , 杨日升 , 田景峰 , 孟福庆 , 李建勋 , 黄洪松
- 申请人: 浙江龙盛化工研究有限公司
- 申请人地址: 浙江省绍兴市上虞市杭州湾工业园区纬三路15号
- 专利权人: 浙江龙盛化工研究有限公司
- 当前专利权人: 浙江鸿盛化工有限公司,浙江龙盛化工研究有限公司
- 当前专利权人地址: 浙江省绍兴市上虞市杭州湾工业园区纬三路15号
- 代理机构: 杭州天正专利事务所有限公司
- 代理人: 黄美娟; 冷红梅
- 主分类号: C07C211/51
- IPC分类号: C07C211/51 ; C07C209/36
The invention provides a method for continuous hydrogenation of dinitrobenzene and recycling of reaction heat thereof. The method comprises the following steps: (1) adopting a plurality of stages of hydrogenation reaction kettles which are connected in series, continuously leading the materials dinitrobenzene and methanol to a first stage of a hydrogenation reaction kettle, and simultaneously leading in hydrogen continuously and adding a catalyst, carrying out a liquid-phase catalytic hydrogenation reaction, and continuously feeding the material from the final stage of hydrogenation reaction kettle to a mature kettle to cure and cool; meanwhile, removing hydrogenation reaction heat by water, so as to obtain hot water of 105-120 DEG C; and (2) orderly carrying out continuous sedimentation, filtering and separation on hydrogenation reduction cooling fluid from the mature kettle, and then recovering and mechanically applying the separated catalyst in cycle, and carrying out dealcoholization, dehydration and rectification on the separated hydrogenation reduction fluid to obtain diaminobenzene. Thus, effective utilization of reaction heat energy is achieved on the premise of efficiently producing the diaminobenzene; the aim of saving energy is achieved.
公开/授权文献:
- CN103360265B 一种二硝基苯连续加氢及其反应热回收利用方法 公开/授权日:2014-12-17
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07C | 无环或碳环化合物 |
------C07C211/00 | 含有与碳架连接的氨基的化合物 |
--------C07C211/01 | .与非环碳原子连接的氨基 |
----------C07C211/44 | ..有与仅有1个六元芳环连接的氨基 |
------------C07C211/45 | ...单胺 |
--------------C07C211/50 | ....有至少两个与碳架的六元芳环的碳原子连接的氨基 |
----------------C07C211/51 | .....苯二胺 |