![生产磺酸二酰胺的方法](/CN/2008/8/22/images/200880111156.jpg)
基本信息:
- 专利标题: 生产磺酸二酰胺的方法
- 专利标题(英):Method for producing sulfonic acid diamides
- 申请号:CN200880111156.X 申请日:2008-10-10
- 公开(公告)号:CN101821233A 公开(公告)日:2010-09-01
- 发明人: A·普勒舍克 , T·施密特 , J·格布哈特 , S·勒尔 , M·凯尔 , J·H·韦威尔斯
- 申请人: 巴斯夫欧洲公司
- 申请人地址: 德国路德维希港
- 专利权人: 巴斯夫欧洲公司
- 当前专利权人: 巴斯夫欧洲公司
- 当前专利权人地址: 德国路德维希港
- 代理机构: 北京市中咨律师事务所
- 代理人: 刘金辉; 林柏楠
- 优先权: 07118416.2 2007.10.12 EP
- 国际申请: PCT/EP2008/063630 2008.10.10
- 国际公布: WO2009/050120 DE 2009.04.23
- 进入国家日期: 2010-04-12
- 主分类号: C07C303/34
- IPC分类号: C07C303/34 ; C07C307/06 ; C07D239/54
The present invention relates to a method for producing sulfonic acid amines of the general formula (I) R1R2N-S(O)2-NH2 (I), where R1 and R2 are independent of each other and stand for a primary alkyl radical having 1 to 8 C atoms, a secondary alkyl radical having 3 to 8 C atoms, or a cycloalkyl radical having 5 to 8 C atoms, or, together with the nitrogen atom, form a 5- to 8-member saturated nitrogen heterocyclic compound that can comprise, in addition to the nitrogen atom, an additional hetero atom, selected from O and S, as a ring member, wherein the nitrogen heterocyclic compound is unsubstituted, or can comprise 1, 2, 3, or 4 alkyl groups each having 1 to 4 C atoms as substituents. The method comprises the following steps: i) conversion of a secondary amine of the formula (II) R1R2NH (II), where R1 and R2 have the meaning indicated above, having sulfuryl chloride in an inert, particularly aromatic, solvent in the presence of a tertiary amine, to form a sulfamoyl chloride of the formula (III) R1R2N-S(O)2-CI (III), where R1 and R2 have the meaning indicated above, and ii) conversion of the sulfamoyl chloride of the formula (III) obtained in step i) using ammonia, wherein in step ii) the sulfamoyl chloride of the formula (III) is used in the form of the solution obtained in step i) in the inert, particularly aromatic, solvent.
公开/授权文献:
- CN101821233B 生产磺酸二酰胺的方法 公开/授权日:2016-06-29
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07C | 无环或碳环化合物 |
------C07C303/00 | 硫酸酯或硫酸酰胺的制备;磺酸或其酯、卤化物、酐或酰胺的制备 |
--------C07C303/34 | .硫酸酰胺的 |