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基本信息:
- 专利标题: 一种丙酮模拟连续逆流吸收乙烯酮工艺
- 专利标题(英):Process for simulative continuous counter-current absorption of ketene by acetone
- 申请号:CN200810204711.5 申请日:2008-12-16
- 公开(公告)号:CN101747163A 公开(公告)日:2010-06-23
- 发明人: 朱家文 , 曾义红 , 武斌 , 叶小鹤 , 顾明兰 , 纪利俊
- 申请人: 上海吴泾化工有限公司 , 华东理工大学
- 申请人地址: 上海市龙吴路4600号
- 专利权人: 上海吴泾化工有限公司,华东理工大学
- 当前专利权人: 上海吴泾化工有限公司,华东理工大学
- 当前专利权人地址: 上海市龙吴路4600号
- 代理机构: 上海申汇专利代理有限公司
- 代理人: 俞宗耀
- 主分类号: C07C45/76
- IPC分类号: C07C45/76 ; C07C49/14 ; C07C49/12
The invention relates to a process for the simulative continuous counter-current absorption of ketene by acetone, which is characterized in that: at least three reactors are arranged, wherein reaction materials, namely the acetone and catalysts are added into the reactors; two reactors are connected in series for reaction and another one reactor is for later use; the three reactors are switched to perform operation in turn; a stirring paddle of each reactor adopts a closed-type bent-blade disk turbine paddle; the simulative continuous counter-current absorption of the ketene is realized through negative pressure; a condenser and a gas-liquid separator are arranged at the back stage of each reactor; gas phase generated during the reaction of the reactors is condensed by the condenser and separated by the gas-liquid separator; and liquid phase flows back to the reactors and the gas phase enters the next-stage reactor. The process has the advantages that: the ketene is absorbed by the negative pressure which is generated by stirring the closed-type bent-blade disk turbine paddle, so the ketene gas delivery pressure and the autopolymerization reaction are reduced, the stirring efficiency is high, and the dispersion effect is good even if thickened catalysts such as ASA and the like exist. A plurality of reactors can be connected in series when necessary to form a certain concentration gradient so as to realize the counter-current absorption.
公开/授权文献:
- CN101747163B 一种丙酮模拟连续逆流吸收乙烯酮工艺 公开/授权日:2013-07-17