
基本信息:
- 专利标题: 氢化甘油的方法
- 专利标题(英):Method for hydrogenating glycerol
- 申请号:CN200880019968.1 申请日:2008-06-11
- 公开(公告)号:CN101687742A 公开(公告)日:2010-03-31
- 发明人: N·克莱因 , A·韦斯特费奇特尔 , M·贝尔
- 申请人: 埃默里油脂化学有限公司
- 申请人地址: 德国杜塞尔多夫
- 专利权人: 埃默里油脂化学有限公司
- 当前专利权人: 埃默里油脂化学有限公司
- 当前专利权人地址: 德国杜塞尔多夫
- 代理机构: 北京市中咨律师事务所
- 代理人: 林柏楠; 刘金辉
- 优先权: 102007027372.1 2007.06.11 DE
- 国际申请: PCT/EP2008/004666 2008.06.11
- 国际公布: WO2008/151784 DE 2008.12.18
- 进入国家日期: 2009-12-11
- 主分类号: C07C29/60
- IPC分类号: C07C29/60 ; C07C31/20 ; C07C41/03 ; C07C43/10 ; C07C67/04 ; C07C69/16 ; C07C269/02 ; C07C271/08 ; B01J8/22 ; F28D19/00
The invention relates to a method for producing 1,2 propandiol by hydrogenation of glycerol using hydrogen gas, wherein glycerol is reacted with hydrogen to give 1,2 propandiol. This reaction is carried out in at least i reactors R1 to Ri that are fluidically interconnected and that have respective hydrogenation catalysts. According to said method, hydrogen gas and a glycerol phase PGlycerin are introduced into the first reactor R1 and a first, preferably gaseous hydrogen phase H1 is formed in the reactor R1. The preferably liquid phase Pn-1 that was formed in the above-mentioned reactor Rn-1and hydrogen are introduced into each of the subsequent reactors Rn, with n being an integer from the range of 2 to i, and a preferably liquid 1,2 propandiol-containing phase Pn and a preferably gaseous hydrogen phase Hn are formed in the reactor Rn, the glycerol phase PGlycerin containing at least 60% by weight of glycerol based on the total weight of the glycerol phase PGlycerin. The invention also relates to the 1,2 propandiol obtainable by this method, to a device for producing 1,2 propandiol, and to a method for producing a compound having at least one ether group, at least one ester group, at least one amino group, at least one urethane group, or at least two thereof.
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07C | 无环或碳环化合物 |
------C07C29/00 | 含羟基或氧—金属基连接碳原子的化合物的制备 |
--------C07C29/60 | .消除羟基,例如脱水 |