基本信息:
- 专利标题： 改进的混合金属氧化物催化剂和（氨解）氧化低级烷烃的方法
- 专利标题（英）：Improved mixed metal oxide catalysts and process for (amm) oxidation of lower alkane hydrocarbons
- 申请号：CN200880017564.9 申请日：2008-04-01
- 公开(公告)号：CN101678327A 公开(公告)日：2010-03-24
- 发明人： 格里·W·扎亚克 , 阿拉柯南达·巴塔查里亚 , 巴豪焦·钱德拉·苏特拉达尔 , 小詹姆斯·F·布拉兹迪尔
- 申请人： 伊内奥斯美国公司
- 申请人地址： 美国伊利诺伊州
- 专利权人： 伊内奥斯美国公司
- 当前专利权人： 伊内奥斯美国公司
- 当前专利权人地址： 美国伊利诺伊州
- 代理机构： 中原信达知识产权代理有限责任公司
- 代理人： 郭国清; 樊卫民
- 优先权： 11/732,213 2007.04.03 US
- 国际申请： PCT/US2008/004227 2008.04.01
- 国际公布： WO2008/123974 EN 2008.10.16
- 进入国家日期： 2009-11-26
- 主分类号： B01J23/28
- IPC分类号： B01J23/28 ; B01J27/057 ; B01J37/00 ; B01J37/02 ; B01J37/08 ; C07C51/215 ; C07C253/24
Catalytic compositions and processes are disclosed for economical conversions of lower alkane hydrocarbons. Broadly, the present invention discloses solid promoter treated compositions containing mixed metal oxides that exhibit catalytic activity for ammoxidation of lower alkane hydrocarbons to produce an unsaturated nitrile in high yield. Generally, these solid oxide compositions comprise, as component elements, molybdenum (Mo), vanadium (V) niobium (Nb) and at least one active element selected from the group consisting of the elements having the ability to form positive ions. Mixed metal oxide catalytic compositions advantageously are formed process steps comprising impregnation of a base catalyst with an aqueous medium comprising sources of one or more promoter element drying the resulting material; and thereafter subjecting the dried material to heat treatment, under a gaseous atmosphere that is substantially free of dioxygen, at elevated temperatures of at least 400 DEG C. Also described are methods for forming the improved catalysts having the desired crystalline structure and ammoxidation processes for conversion of lower alkanes.
IPC结构图谱:
| B | 作业；运输 |
| --B01 | 一般的物理或化学的方法或装置 |
| ----B01J | 化学或物理方法，例如，催化作用、胶体化学；其有关设备 |
| ------B01J23/00 | 不包含在B01J21/00组中的，包含金属或金属氧化物或氢氧化物的催化剂 |
| --------B01J23/16 | .砷、锑、铋、钒、铌、钽、钋、铬、钼、钨、锰、锝或铼的 |
| ----------B01J23/20 | ..钒、铌或钽 |
| ------------B01J23/28 | ...钼 |