
基本信息:
- 专利标题: 一种负载型双硅桥茂金属催化剂及其制备方法和应用
- 专利标题(英):Supported bis-silicon-bridged metallocene catalyst, preparation method and application thereof
- 申请号:CN200810117485.7 申请日:2008-07-31
- 公开(公告)号:CN101638447A 公开(公告)日:2010-02-03
- 发明人: 米普科 , 钱锦华 , 许胜 , 王斯晗 , 邢秋菊 , 张德顺 , 郭翔 , 刘敏 , 张琰 , 阎修维 , 卢攀峰
- 申请人: 中国石油天然气股份有限公司 , 华东理工大学
- 申请人地址: 北京市东城区安德路16号洲际大厦
- 专利权人: 中国石油天然气股份有限公司,华东理工大学
- 当前专利权人: 中国石油天然气股份有限公司,华东理工大学
- 当前专利权人地址: 北京市东城区安德路16号洲际大厦
- 代理机构: 北京市中实友知识产权代理有限责任公司
- 代理人: 谢小延
- 主分类号: C08F4/6592
- IPC分类号: C08F4/6592 ; C08F10/02
The invention relates to a supported bis-silicon-bridged metallocene catalyst, a preparation method and application thereof. The catalyst consists of a bis-silicon-bridged metallocene compound, an alkyl aluminum compound or alkyl aluminum or a mixture of the alkyl aluminum compound and the alkyl aluminum, and an inert inorganic compound carrier, wherein a transitional metal of metal zirconium or titanium of the bis-silicon-bridged metallocene compound accounts for 0.45 to 0.70 percent of the 100 percent of the total weight; aluminum of the an alkyl aluminum compound or alkyl aluminum or a mixture of the alkyl aluminum compound and the alkyl aluminum accounts for 15 to 20 percents of 100 percent of the total weight; and the inert inorganic compound carrier accounts for the balance of the 100 percent of the total weight. The catalyst is used for all polymerization processes of ethylene or the ethylene and alpha-olefin with 3 to 20 carbon atoms (comprising the processes of gas phase polymerization, slurry polymerization and solution polymerization); the catalyst is used for the copolymerization of the ethylene or the ethylene and the alpha-olefin with 3 to 20 carbon atoms, the homopolymerization of the ethylene, or the copolymerization of the ethylene and alpha-olefin with 4 to 12 carbon atoms, the gas phase copolymerization of the ethylene and hexene-1, the slurry copolymerization of the ethylene and the hexene-1, and the solution polymerization process of the ethylene and octylene-1; and the alpha-olefin has higher contents in a copolymer.
公开/授权文献:
- CN101638447B 一种负载型双硅桥茂金属催化剂及其制备方法和应用 公开/授权日:2011-10-05
IPC结构图谱:
C | 化学;冶金 |
--C08 | 有机高分子化合物;其制备或化学加工;以其为基料的组合物 |
----C08F | 仅用碳—碳不饱和键反应得到的高分子化合物 |
------C08F4/00 | 聚合催化剂 |
--------C08F4/42 | .金属;金属氢化物;金属有机化合物;及其作为催化剂母体的用途 |
----------C08F4/44 | ..选自轻金属、锌、镉、汞、铜、银、金、硼、镓、铟、铊、稀土元素或锕族元素 |
------------C08F4/60 | ...与高熔点金属、铁族金属、铂族金属、锰、锝、铼或它们的化合物在一起 |
--------------C08F4/607 | ....含有一种特殊的非金属或不含金属化合物的催化剂 |
----------------C08F4/627 | .....催化剂含有一种特殊的非金属或不含金属的化合物 |
------------------C08F4/647 | ......催化剂含有一种特殊的非金属或不含金属的化合物 |
--------------------C08F4/6592 | .......至少含1个环戊二烯环,稠合的或未稠合的,例如,茚基环或芴基环 |