
基本信息:
- 专利标题: 合成N,N-二甲基-1,3-二氨基丙烷(DMAPA)的方法
- 专利标题(英):N, n-dimethyl-1,3-diaminopropane (DMAPA) synthesizing method
- 申请号:CN200680045411.6 申请日:2006-10-31
- 公开(公告)号:CN101321722B 公开(公告)日:2012-07-18
- 发明人: M·恩斯特 , S·厄伦施莱格 , F·库恩克 , K-H·罗斯 , R·德格 , J-P·梅尔德
- 申请人: 巴斯夫欧洲公司
- 申请人地址: 德国路德维希港
- 专利权人: 巴斯夫欧洲公司
- 当前专利权人: 巴斯夫欧洲公司
- 当前专利权人地址: 德国路德维希港
- 代理机构: 北京市中咨律师事务所
- 代理人: 林柏楠; 刘金辉
- 优先权: 102005052457.5 2005.11.03 DE
- 国际申请: PCT/EP2006/067952 2006.10.31
- 国际公布: WO2007/051786 DE 2007.05.10
- 进入国家日期: 2008-06-03
- 主分类号: C07C209/48
- IPC分类号: C07C209/48 ; B01J10/00 ; C07C211/11 ; B01D3/14
The invention relates to a diamine industrially producing method from a corresponding alkenile-nitrile which contains at least one C-C double bond consisting (a) in reacting the alkenile-nitrile in a first reactor with a corresponding monoamine by exothermally adding a monoamine to said double bond in such a way that an aminoalkyle nitrile is obtained, wherein the monoamine and water are providedand the alkenile-nitrile is added, (b) in evaporating the unreacted alkenile-nitrile and aminoalkyle for enriching the aminoalkyle nitrile produces in the sump of the first reactor, (c) in transferring the aminoalkyle nitrile bottom product of the step (b) to a second reactor, (d) in batchwisely catalytically hydrogenating the aminoalkyle nitrile transferred at the step (c) in such a way that a diamine is produced in the second reactor, wherein for each batch,; an appropriate catalyst and water for hydrogenating nitrils into amines, a desired diamine and a base are provided, the second reactor is supplied with hydrogen and the aminoalkyle nitrile transferred at the step (c) is proportioned therein, and (e) in extracting the diamine and in possibly repeating the steps from (a) to (e). A device for producing the diamine and the use of the devices are also disclosed. The preferred diamine is embodied in the form of a 3-dimethylaminopropylamine (DMAPA).
公开/授权文献:
- CN101321722A 合成N,N-二甲基-1,3-二氨基丙烷(DMAPA)的方法 公开/授权日:2008-12-10
IPC结构图谱:
C | 化学;冶金 |
--C07 | 有机化学 |
----C07C | 无环或碳环化合物 |
------C07C209/00 | 含氨基连接在碳架上的化合物的制备 |
--------C07C209/04 | .用氨基取代官能团 |
----------C07C209/48 | ..腈的还原 |